Jul 01 1979 · Many highly sensitive flotation spectrophotometric methods for determi nation of various elements have been developed recently 4 On shaking the aqueous solution with a slightly polar solvent the sparingly soluble ion associate precipitates at the phase boundary After separation of the liquid phases the precipitate can be dissolved in a
A simple and sensitive spectrophotometric procedure for the determination of microgram amounts of silver has been developed The method is based on the flotation of the complex of Schiff base 22mercaptophenyliminomethylphenol MPMP and silver at the aqueous solutionchloroform interface The complex was then separated and dissolved in 5 mL of methanol and its absorbance was
Abstract A simple fast reproducible and sensitive method for the flotation spectrophotometric determination of Al 3 is reported The apparent molar absorptivity ε of the ion associate was determined to be 835 ×10 4 L mol −1 cm1 The calibration curve was linear in
simple sensitive and accurate procedure for the preconcen Spectrophotometry still represents an attractive technique for the determination of metal ions in aqueous media because of its simplicity being inexpensive and more readily avail Selective FlotationSpectrophotometric Determination of
A sensitive and precise method for the determination of microgram amounts of palladium based on the ion associate of the anionic palladiumIIthiocyanate complex with Methylene Blue MB has been developed The ion associate is floated with benzene and dissolved in acetone and its molar absorptivity is
The extraction and preconcentration of a metal complex via surfactantmediated phase separation was studied A sensitive selective and lowcost methodology for the determination of microamounts of Lanthanum and Yttrium using alizarin red sulfonate ARS with a flotation step prior to absorptiometric determination was developed
Dec 20 2010 · The present study describes a simple and highly selective method for separation preconcentration and spectrophotometric determination of extremely low concentrations of lead It is based on flotation of a complex of Pb 2 ions and Alizarin yellow between aqueous and nhexane interface at pH 6 The proposed procedure is also applied for
In previous studies the authors had developed some sensitive determination methods for phosphate ie extractionindirect atomic absorption spectrophotometry using copperIIl10phenanthroline complex 7 flotationspectrophotometry 8 flotationindirect atomic absorption spectrophotometry 9 spectrophotometry following membrane filter
This paper describes a sensitive spectrophotometric method for the determination of mercury based on the flotation of a mercury iodidebrilliant green complex with cyclohexane at pH 5 and dissolution of the complex in acetone The absorbance of the complex is measured at 625 nm Beers law is obeyed from 4–500 μgl of mercury The method is highly sensitive ɛ 596 × 105 1 mol−1 cm
A method of flotation separation with subsequent sensitive spectrophotometric determination of niobium is developed In the presence of oxalate niobium and 35dinitrocatechol form an anionic complex able to associate with Rhodamine B RB The niobium compound is floated with cyclohexane dissolved in acetone and the absorbance of the solution is measured at 555 nm
A simple fast reproducible and sensitive method for the flotation spectrophotometric determination of Al 3 is reported The apparent molar absorptivity ε of the ion associate was determined to be 835×10 4 L mol 1 cm 1 The calibration curve was linear in the concentration range of 1050 ng mL 1sup of Alsup3sup with a correlation coefficient of 09997
INTRODUCTION Flotationspectrophotometry probably provides one of the most sensitive relatively simple and fast approach to trace analysis 1 Ionassociation systems in a more general way could be said to result from the interaction of charged particles or complexes with oppositely charged ions When a quaternary ammonium containing compound is used the primary complex produced is cation
A simple fast reproducible and sensitive method for the flotationspectrophotometric determination of Pb2 is reported The method is based on the ternary ionassociation of Pb2 xylenol orange XO and cetyltrimethylammonium bromide CTAB which is floated at interface of aqueous phase and nhexane by shaking the separating funnel By discarding the aqueous solution the more dense phase
The separated and washed compound readily dissolves in acetone giving an intensely coloured solution which forms the basis for a sensitive spectrophotometric determination of vanadium The molar absorptivity is 21x105 mol1 cm1 at 555 nm and the detection limit is 3ngml Beers law is obeyed up to a vanadium concentration of 03 jigml
Flotation spectrophotometry allows one to preconcentrate the trace elements in various materials 9–24 Primary investigations showed that the none of two usual complexes of Ni and DMG could not float completely in interface of liquid and organic phase due to solubility in water and organic phase of NiDm 3 2and NiHDm 2 respectively Thus
A method of flotation separation with subsequent sensitive spectrophotometric determination of niobium is developed In the presence of oxalate niobium and 35dinitrocatechol form an anionic complex able to associate with Rhodamine B RB The niobium compound is floated with cyclohexane dissolved in acetone and the absorbance of the solution is measured at 555 nm
Aluminium was determined in a weakly alkaline medium by reaction with alizarin at trace level Flotation of the complex was carried out with heptane followed by dissolution in N Ndimethylformamide DMF for subsequent spectrophotometric determination The molar absorptivity was 292×10 5 mol − cm − at 518 run Beers law was obeyed in
Sensitive flotationspectrophotometric determination of Apr 01 1985 Some of the most sensitive spectrophotometric methods of gold determination yet reported are based on the extraction of ionpairs of AuCl or AuBr with univalent basic dye cations17 the Rhodamine B method s 97 x 104 being the best known the determination with thio
Application of Flotation and Spectrophotometric Detection for Preconcentration and Separation of Trace Amounts of Cadmium Ion Using a New Ligand 31H indole3yle Due to high toxicity of cadmium a sensitive and accurate analytical method is required for
pertonic effects exerted by the flotation solution The methods most frequently used to recover parasite eggs and oocysts are flotation techniques that rely on the differences in the specific gravity SG of the eggs fecal debris and flotation solution The SG of most parasite eggs is between 105 and 1231 For parasite eggs to float the
Dec 20 2010 · The present study describes a simple and highly selective method for separation preconcentration and spectrophotometric determination of extremely low concentrations of lead It is based on flotation of a complex of Pb2 ions and Alizarin yellow between aqueous and nhexane interface at pH 6
